Information card for entry 4076802

Structure parameters

• Chemical name: Pentacarbonyl(eta$2!-methoxyvinyl-gold(I)triphenylphosphine-C,C') chromium(0)
• Formula: C26 H20 Au Cr O6 P
• Calculated formula: C26 H20 Au Cr O6 P
• SMILES: [CH2](=[C]1(OC)[Au][P](c2ccccc2)(c2ccccc2)c2ccccc2)[Cr]1(C#[O])(C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: Electrophilic Addition of Ph3PAu+to Anionic Alkoxy Fischer-Type Carbene Complexes: A Novel Approach to Metal-Stabilized Bimetallic Vinyl Ether Complexes
• Authors of publication: Raubenheimer, Helgard G.; Esterhuysen, Matthias W.; Timoshkin, Alexey; Chen, Yu; Frenking, Gernot
• Journal of publication: Organometallics
• Year of publication: 2002
• Journal volume: 21
• Journal issue: 15
• Pages of publication: 3173
• a: 10.6147 ± 0.0004 Å
• b: 12.0314 ± 0.0004 Å
• c: 20.458 ± 0.0009 Å
• α: 90°
• β: 99.705 ± 0.002°
• γ: 90°
• Cell volume: 2575.29 ± 0.17 ų
• Cell temperature: 172 ± 2 K
• Ambient diffraction temperature: 172 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0957
• Residual factor for significantly intense reflections: 0.0454
• Weighted residual factors for significantly intense reflections: 0.0738
• Weighted residual factors for all reflections included in the refinement: 0.0867
• Goodness-of-fit parameter for all reflections included in the refinement: 1.01
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No