Information card for entry 4077448

Structure parameters

• Formula: C25 H45 F6 N2 O P Ru Si
• Calculated formula: C25 H45 F6 N2 O P Ru Si
• SMILES: [Ru]123456([N](C(C)C)=C(N(C(C)C)C6[Si](C)(C)C)C)([c]6([c]5([c]4([c]3([c]2([c]16C)C)C)C)C)C)C#[O].[P](F)(F)(F)(F)(F)[F-]
• Title of publication: Ruthenium Amidinato−Carbene Complexes Containing a Ru−Si Bond: Formation and Reversible α-Silyl Group Migration from the Metal to the Carbene Ligand
• Authors of publication: Hayashida, Taizo; Nagashima, Hideo
• Journal of publication: Organometallics
• Year of publication: 2001
• Journal volume: 20
• Journal issue: 24
• Pages of publication: 4996
• a: 22.25 ± 0.004 Å
• b: 9.234 ± 0.003 Å
• c: 15.137 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3110 ± 1.3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 8
• Space group number: 33
• Hermann-Mauguin space group symbol: P n a 21
• Hall space group symbol: P 2c -2n
• Residual factor for all reflections: 0.1777
• Residual factor for significantly intense reflections: 0.0498
• Weighted residual factors for significantly intense reflections: 0.1263
• Weighted residual factors for all reflections included in the refinement: 0.173
• Goodness-of-fit parameter for all reflections included in the refinement: 0.898
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No