Information card for entry 4077509

Structure parameters

• Formula: C28 H63 B F4 O4 Os2 P2
• Calculated formula: C28 H47 B F4 O4 Os2 P2
• SMILES: [Os]1234([P](C(C)C)(C(C)C)C(C)C)([OH][Os]56([P](C(C)C)(C(C)C)C(C)C)([OH]1)([O]=C(O2)C)([CH2]=[CH2]5)[CH2]=[CH2]6)([CH2]=[CH2]3)[CH2]=[CH2]4.[B](F)(F)(F)[F-]
• Title of publication: Reaction of a Cationic Osmium(IV) Dihydride with Ethylene: Formation and Structure of the Novel Tetraethylene Dimer Complex [{(PiPr3)(η2-C2H4)2Os}2(μ-OH)2(μ-O2CCH3)]BF4
• Authors of publication: Esteruelas, Miguel A.; García-Yebra, Cristina; Oliván, Montserrat; Oñate, Enrique
• Journal of publication: Organometallics
• Year of publication: 2000
• Journal volume: 19
• Journal issue: 16
• Pages of publication: 3260 - 3262
• a: 15.371 ± 0.003 Å
• b: 11.934 ± 0.003 Å
• c: 19.36 ± 0.005 Å
• α: 90°
• β: 90 ± 0.01°
• γ: 90°
• Cell volume: 3551.4 ± 1.5 ų
• Cell temperature: 200 ± 0.2 K
• Ambient diffraction temperature: 200 ± 0.2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0858
• Residual factor for significantly intense reflections: 0.0488
• Weighted residual factors for significantly intense reflections: 0.1023
• Weighted residual factors for all reflections included in the refinement: 0.1162
• Goodness-of-fit parameter for all reflections included in the refinement: 1.02
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No