Information card for entry 4077718

Structure parameters

• Chemical name: [tetrakis(μ-trifluoroacetato-κO,κO')dirhodium(II,II)]-bis- (η2-diphenylacetylene)
• Formula: C36 H20 F12 O8 Rh2
• Calculated formula: C36 H20 F12 O8 Rh2
• Title of publication: Studies of Dirhodium(II) Tetrakis(trifluoroacetate). 6. The First Structural Characterization of Axial Alkyne Complexes, Rh2(O2CCF3)4(Ph2C2)n(n= 1, 2): Diphenylacetylene as a Bifunctional Ligand
• Authors of publication: Cotton, F. Albert; Dikarev, Evgeny V.; Petrukhina, Marina A.; Stiriba, Salah-Eddine
• Journal of publication: Organometallics
• Year of publication: 2000
• Journal volume: 19
• Journal issue: 7
• Pages of publication: 1402
• a: 24.7 ± 0.001 Å
• b: 9.7055 ± 0.0005 Å
• c: 18.5448 ± 0.0004 Å
• α: 90°
• β: 124.368 ± 0.002°
• γ: 90°
• Cell volume: 3669.6 ± 0.3 ų
• Cell temperature: 213 ± 2 K
• Ambient diffraction temperature: 213 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0379
• Residual factor for significantly intense reflections: 0.0359
• Weighted residual factors for all reflections: 0.0874
• Weighted residual factors for significantly intense reflections: 0.085
• Goodness-of-fit parameter for all reflections: 1.027
• Goodness-of-fit parameter for significantly intense reflections: 1.034
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No