Information card for entry 4077975

Structure parameters

• Common name: palladium-thallium carbonylphosphine acetylacetonate
• Formula: C123.2 H99.4 O11.3 P6 Pd9 Tl
• Calculated formula: C122.3 H98.65 O11.3 P6 Pd9 Tl
• Title of publication: High-Yield Synthesis of PPh3-Ligated Decanuclear Tl‒Pd Cluster, Pd9[Tl(acac)](CO)9(PPh3)6: Comparative Analysis of Tl(I)‒Pd(0) Bonding Connectivities with Known Tl‒Pd Clusters and Resulting Insight Concerning Their Dissimilar Dynamic Solution Behavior
• Authors of publication: Mednikov, Evgueni G.; Vo, Nicky; Fry, Charles G.; Dahl, Lawrence F.
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 7
• Pages of publication: 2878
• a: 16.6815 ± 0.0005 Å
• b: 23.9936 ± 0.0007 Å
• c: 30.323 ± 0.0009 Å
• α: 107.682 ± 0.002°
• β: 92.176 ± 0.002°
• γ: 99.572 ± 0.002°
• Cell volume: 11351.7 ± 0.6 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0657
• Residual factor for significantly intense reflections: 0.0448
• Weighted residual factors for significantly intense reflections: 0.1331
• Weighted residual factors for all reflections included in the refinement: 0.1506
• Goodness-of-fit parameter for all reflections included in the refinement: 1.078
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No