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Information card for entry 4078333
Preview
Coordinates | 4078333.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C20 H14 Mo2 O7 Ru |
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Calculated formula | C20 H14 Mo2 O7 Ru |
SMILES | [Mo]123456([Ru]78([Mo]9%10%11%121(C#[O])(C#[O])([cH]1[cH]%12[cH]%11[cH]%10[cH]91)[C]67=[CH]8C)(C#[O])(C#[O])C#[O])(C#[O])(C#[O])[cH]1[cH]2[cH]3[cH]4[cH]51 |
Title of publication | Rearrangement and Scission of Terminal Alkynes in Dimolybdenum Complexes on Reaction with Ruthenium Carbonyl: Formation of Trinuclear Vinylidene and Hexanuclear Bis(alkylidyne) Clusters |
Authors of publication | Adams, Harry; Gill, Louise J.; Morris, Michael J. |
Journal of publication | Organometallics |
Year of publication | 1996 |
Journal volume | 15 |
Journal issue | 20 |
Pages of publication | 4182 |
a | 9.307 ± 0.001 Å |
b | 16.19 ± 0.002 Å |
c | 13.955 ± 0.001 Å |
α | 90° |
β | 96.35 ± 0.01° |
γ | 90° |
Cell volume | 2089.8 ± 0.4 Å3 |
Cell temperature | 293 ± 2 K |
Ambient diffraction temperature | 293 ± 2 K |
Number of distinct elements | 5 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/n 1 |
Hall space group symbol | -P 2yn |
Residual factor for all reflections | 0.0498 |
Residual factor for significantly intense reflections | 0.0476 |
Weighted residual factors for all reflections | 0.1225 |
Weighted residual factors for significantly intense reflections | 0.1205 |
Goodness-of-fit parameter for all reflections | 1.274 |
Goodness-of-fit parameter for significantly intense reflections | 1.294 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4078333.html
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Users of the data should acknowledge the original authors of the
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