Information card for entry 4078371

Structure parameters

• Formula: C23 H53 Cl O Os P2 Si
• Calculated formula: C23 H53 Cl O Os P2 Si
• SMILES: [OsH](Cl)(=C[Si](C)(C)C)(C#[O])([P](C(C)C)(C(C)C)C(C)C)[P](C(C)C)(C(C)C)C(C)C
• Title of publication: Stable Osmium Hydrido−Carbene Complexes with CH2and Secondary Carbenes CHR as Ligands
• Authors of publication: Werner, Helmut; Stüer, Wolfram; Laubender, Matthias; Lehmann, Christopher; Herbst-Irmer, Regine
• Journal of publication: Organometallics
• Year of publication: 1997
• Journal volume: 16
• Journal issue: 11
• Pages of publication: 2236
• a: 9.101 ± 0.002 Å
• b: 16.847 ± 0.003 Å
• c: 20.226 ± 0.003 Å
• α: 90°
• β: 93.74 ± 0.02°
• γ: 90°
• Cell volume: 3094.5 ± 1 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0456
• Residual factor for significantly intense reflections: 0.0283
• Weighted residual factors for all reflections: 0.0592
• Weighted residual factors for significantly intense reflections: 0.0577
• Goodness-of-fit parameter for all reflections: 0.927
• Goodness-of-fit parameter for significantly intense reflections: 1.078
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No