Information card for entry 4078670

Structure parameters

• Formula: C30 H56 Ir O3 P4 Rh Si
• Calculated formula: C30 H56 Ir O3 P4 Rh Si
• Title of publication: Multiple Si‒H Bond Activations in a Bis(diethylphosphino)methane-Bridged Complex of Rhodium and Iridium: Synthesis of an Unusual Bis(silyl)/μ-Silylene Complex
• Authors of publication: Mobarok, Md Hosnay; Ferguson, Michael J.; Cowie, Martin
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 13
• Pages of publication: 4722
• a: 11.5032 ± 0.0004 Å
• b: 17.1496 ± 0.0006 Å
• c: 18.5262 ± 0.0006 Å
• α: 90°
• β: 97.0573 ± 0.0004°
• γ: 90°
• Cell volume: 3627.1 ± 0.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.019
• Residual factor for significantly intense reflections: 0.0178
• Weighted residual factors for significantly intense reflections: 0.0446
• Weighted residual factors for all reflections included in the refinement: 0.045
• Goodness-of-fit parameter for all reflections included in the refinement: 1.107
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No