Information card for entry 4078689

Structure parameters

• Common name: jonkm05
• Chemical name: Pt(dippe)(eta2-vinylOAc)
• Formula: C18 H38 O2 P2 Pt
• Calculated formula: C18 H38 O2 P2 Pt
• SMILES: [Pt]12([P](CC[P]1(C(C)C)C(C)C)(C(C)C)C(C)C)[CH2]=[CH]2OC(=O)C
• Title of publication: Carbon‒Oxygen Bond Activation in Esters by Platinum(0): Cleavage of the Less Reactive Bond
• Authors of publication: Manbeck, Kimberly A.; Kundu, Sabuj; Walsh, Aaron P.; Brennessel, William W.; Jones, William D.
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 14
• Pages of publication: 5018
• a: 9.1218 ± 0.0007 Å
• b: 15.4549 ± 0.0011 Å
• c: 15.8172 ± 0.0012 Å
• α: 90°
• β: 104.412 ± 0.001°
• γ: 90°
• Cell volume: 2159.7 ± 0.3 ų
• Cell temperature: 100 ± 0.1 K
• Ambient diffraction temperature: 100 ± 0.1 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.027
• Residual factor for significantly intense reflections: 0.0201
• Weighted residual factors for significantly intense reflections: 0.0429
• Weighted residual factors for all reflections included in the refinement: 0.0449
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No