Information card for entry 4078786

Structure parameters

• Formula: C53.5 H70.25 I2 N6.75 Rh2
• Calculated formula: C53.5 H70.25 I2 N6.75 Rh2
• Title of publication: Di-Mesoionic Carbene-Bridged Complexes of Rh2, Ir2, and RhIr: A Stepwise Metalation Strategy for the Synthesis of di-MIC-Bridged Mixed-Metal Systems
• Authors of publication: Zamora, Matthew T.; Ferguson, Michael J.; Cowie, Martin
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 15
• Pages of publication: 5384
• a: 11.0441 ± 0.0002 Å
• b: 15.0942 ± 0.0003 Å
• c: 17.8573 ± 0.0004 Å
• α: 69.8435 ± 0.0009°
• β: 85.4295 ± 0.0011°
• γ: 89.9816 ± 0.0012°
• Cell volume: 2784.47 ± 0.1 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0805
• Residual factor for significantly intense reflections: 0.0704
• Weighted residual factors for significantly intense reflections: 0.1631
• Weighted residual factors for all reflections included in the refinement: 0.1732
• Goodness-of-fit parameter for all reflections included in the refinement: 1.05
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No