Information card for entry 4078816

Structure parameters

• Formula: C57.5 H54 Cl N P4 W
• Calculated formula: C57.5 H50 Cl N P4 W
• Title of publication: Tungsten(II) Alkylimido Complexes from Insertion of Nitriles into Tungsten Hydride: Alkylideneamido Intermediate Stage and Nitrene Group Transfer to Isocyanide
• Authors of publication: Dai, Qi Xiu; Seino, Hidetake; Mizobe, Yasushi
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 14
• Pages of publication: 4933
• a: 11.3227 ± 0.0005 Å
• b: 17.3114 ± 0.001 Å
• c: 24.5617 ± 0.0011 Å
• α: 90°
• β: 95.2165 ± 0.001°
• γ: 90°
• Cell volume: 4794.4 ± 0.4 ų
• Cell temperature: 113.1 K
• Ambient diffraction temperature: 113.1 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for significantly intense reflections: 0.0281
• Weighted residual factors for all reflections included in the refinement: 0.06
• Goodness-of-fit parameter for all reflections included in the refinement: 1.004
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No