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Information card for entry 4080056
Preview
Coordinates | 4080056.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C33 H36 O2 Si W |
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Calculated formula | C33 H36 O2 Si W |
SMILES | [W]12345([Si]([C]61=CC=C(C=C6)C)(c1ccc(cc1)C)c1ccc(cc1)C)(C#[O])(C#[O])[c]1([c]3([c]4([c]5([c]21C)C)C)C)C |
Title of publication | (η3-α-Silabenzyl)tungsten Complexes: An Isolable Intermediate for Interconversion between a Silylene Complex and a Silyl Complex through 1,2-Aryl Migration |
Authors of publication | Suzuki, Eiji; Komuro, Takashi; Kanno, Yuto; Tobita, Hiromi |
Journal of publication | Organometallics |
Year of publication | 2013 |
Journal volume | 32 |
Journal issue | 3 |
Pages of publication | 748 |
a | 8.4262 ± 0.0001 Å |
b | 32.5783 ± 0.0003 Å |
c | 10.4163 ± 0.0001 Å |
α | 90° |
β | 92.2999 ± 0.0004° |
γ | 90° |
Cell volume | 2857.09 ± 0.05 Å3 |
Cell temperature | 150 ± 2 K |
Ambient diffraction temperature | 150 ± 2 K |
Number of distinct elements | 5 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.0374 |
Residual factor for significantly intense reflections | 0.0323 |
Weighted residual factors for significantly intense reflections | 0.0957 |
Weighted residual factors for all reflections included in the refinement | 0.106 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.278 |
Diffraction radiation wavelength | 0.71069 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4080056.html
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Users of the data should acknowledge the original authors of the
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