Information card for entry 4080301

Structure parameters

• Common name: [Sm(DippForm)2Me(THF)]
• Formula: C55 H81 Cl0 N4 O Sm
• Calculated formula: C55 H81 N4 O Sm
• SMILES: [Sm]12([O]3CCCC3)(N(C=[N]1c1c(cccc1C(C)C)C(C)C)c1c(cccc1C(C)C)C(C)C)(N(C=[N]2c1c(cccc1C(C)C)C(C)C)c1c(cccc1C(C)C)C(C)C)C
• Title of publication: Bulky Formamidinate-Supported Lanthanoid Halides and Alkyls, Including a Rare Terminal La‒Me Species
• Authors of publication: Cole, Marcus L.; Deacon, Glen B.; Junk, Peter C.; Wang, Jun
• Journal of publication: Organometallics
• Year of publication: 2013
• Journal volume: 32
• Journal issue: 5
• Pages of publication: 1370
• a: 11.238 ± 0.002 Å
• b: 14.685 ± 0.003 Å
• c: 16.382 ± 0.003 Å
• α: 83.97 ± 0.03°
• β: 77.94 ± 0.03°
• γ: 80.91 ± 0.03°
• Cell volume: 2603.4 ± 0.9 ų
• Cell temperature: 123 ± 1 K
• Ambient diffraction temperature: 123 ± 1 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0666
• Residual factor for significantly intense reflections: 0.0442
• Weighted residual factors for significantly intense reflections: 0.0839
• Weighted residual factors for all reflections included in the refinement: 0.0904
• Goodness-of-fit parameter for all reflections included in the refinement: 1.005
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No