Information card for entry 4080304

Structure parameters

• Common name: [La(DippForm)3]
• Formula: C94 H113 D12 La N6
• Calculated formula: C81 H111 La N6
• SMILES: [La]123(N(C=[N]1c1c(cccc1C(C)C)C(C)C)c1c(cccc1C(C)C)C(C)C)(N(C=[N]2c1c(cccc1C(C)C)C(C)C)c1c(cccc1C(C)C)C(C)C)N(C=[N]3c1c(cccc1C(C)C)C(C)C)c1c(cccc1C(C)C)C(C)C.c1ccccc1
• Title of publication: Bulky Formamidinate-Supported Lanthanoid Halides and Alkyls, Including a Rare Terminal La‒Me Species
• Authors of publication: Cole, Marcus L.; Deacon, Glen B.; Junk, Peter C.; Wang, Jun
• Journal of publication: Organometallics
• Year of publication: 2013
• Journal volume: 32
• Journal issue: 5
• Pages of publication: 1370
• a: 13.033 ± 0.003 Å
• b: 37.741 ± 0.008 Å
• c: 16.757 ± 0.003 Å
• α: 90°
• β: 96.42 ± 0.03°
• γ: 90°
• Cell volume: 8191 ± 3 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.073
• Residual factor for significantly intense reflections: 0.0464
• Weighted residual factors for significantly intense reflections: 0.1058
• Weighted residual factors for all reflections included in the refinement: 0.113
• Goodness-of-fit parameter for all reflections included in the refinement: 1.019
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: Synchrotron
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No