Stable Ionic Rh(I,II,III) Complexes Ligated by an Imidazolium-Substituted Phosphine with π-Acceptor Character: Synthesis, Characterization, and Application to Hydroformylation
Authors of publication
You, Hongxing; Wang, Yongyong; Zhao, Xiaoli; Chen, Shengjie; Liu, Ye
Journal of publication
Organometallics
Year of publication
2013
Journal volume
32
Journal issue
9
Pages of publication
2698
a
10.972 ± 0.002 Å
b
12.542 ± 0.002 Å
c
15.935 ± 0.003 Å
α
90°
β
90°
γ
90°
Cell volume
2192.8 ± 0.7 Å3
Cell temperature
296 ± 2 K
Ambient diffraction temperature
296 ± 2 K
Number of distinct elements
5
Space group number
19
Hermann-Mauguin space group symbol
P 21 21 21
Hall space group symbol
P 2ac 2ab
Residual factor for all reflections
0.0638
Residual factor for significantly intense reflections
0.0541
Weighted residual factors for significantly intense reflections
0.1494
Weighted residual factors for all reflections included in the refinement
0.1603
Goodness-of-fit parameter for all reflections included in the refinement