Information card for entry 4081448

Structure parameters

• Formula: C56 H44 O4 P4 Pt4
• Calculated formula: C56 H44 O4 P4 Pt4
• SMILES: C(#[O])[Pt]12[P](C(=C)[P](c3ccccc3)(c3ccccc3)[Pt]1([Pt]1(C#[O])[P](c3ccccc3)(c3ccccc3)C(=C)[P](c3ccccc3)(c3ccccc3)[Pt]21C#[O])C#[O])(c1ccccc1)c1ccccc1
• Title of publication: Tetrahedral [HnPt4(CO)4(P∧P)2]n+(n= 1, 2; P∧P = CH2═C(PPh2)2) Cationic Mono- and Dihydrido Carbonyl Clusters Obtained by Protonation of the Neutral Pt4(CO)4(P∧P)2
• Authors of publication: Ciabatti, Iacopo; Femoni, Cristina; Iapalucci, Maria Carmela; Longoni, Giuliano; Zacchini, Stefano
• Journal of publication: Organometallics
• Year of publication: 2013
• Journal volume: 32
• Journal issue: 18
• Pages of publication: 5180
• a: 13.612 ± 0.002 Å
• b: 17.153 ± 0.003 Å
• c: 22.77 ± 0.004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5316.5 ± 1.5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 56
• Hermann-Mauguin space group symbol: P c c n
• Hall space group symbol: -P 2ab 2ac
• Residual factor for all reflections: 0.0885
• Residual factor for significantly intense reflections: 0.0535
• Weighted residual factors for significantly intense reflections: 0.1206
• Weighted residual factors for all reflections included in the refinement: 0.1355
• Goodness-of-fit parameter for all reflections included in the refinement: 1.053
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No