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Information card for entry 4081589
Preview
Coordinates | 4081589.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C61 H49 F2 Fe O3 P3 Pt |
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Calculated formula | C61 H49 F2 Fe O3 P3 Pt |
SMILES | c1(ccccc1)[P](c1ccccc1)(c1ccccc1)[Pt]12[CH]3=[C]4(C(=O)[Fe]134(C#[O])(C#[O])[P](C[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)c1ccc(cc1F)F.Cc1ccccc1 |
Title of publication | Reactivity of Silyl-Substituted Iron‒Platinum Hydride Complexes toward Unsaturated Molecules: 4. Insertion of Fluorinated Aromatic Alkynes into the Platinum‒Hydride Bond. Synthesis and Reactivity of Heterobimetallic Dimetallacylopentenone, Dimetallacyclobutene, μ-Vinylidene, and μ2-σ-Alkenyl Complexes |
Authors of publication | Jourdain, Isabelle; Knorr, Michael; Strohmann, Carsten; Unkelbach, Christian; Rojo, Saúl; Gómez-Iglesias, Patricia; Villafañe, Fernando |
Journal of publication | Organometallics |
Year of publication | 2013 |
Journal volume | 32 |
Journal issue | 19 |
Pages of publication | 5343 |
a | 11.74473 ± 0.00016 Å |
b | 13.5156 ± 0.0002 Å |
c | 18.1043 ± 0.0003 Å |
α | 74.7363 ± 0.0013° |
β | 76.9679 ± 0.0013° |
γ | 77.3952 ± 0.0012° |
Cell volume | 2662.18 ± 0.07 Å3 |
Cell temperature | 173 ± 2 K |
Ambient diffraction temperature | 173 ± 2 K |
Number of distinct elements | 7 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.036 |
Residual factor for significantly intense reflections | 0.0296 |
Weighted residual factors for significantly intense reflections | 0.0766 |
Weighted residual factors for all reflections included in the refinement | 0.0781 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.008 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4081589.html
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Users of the data should acknowledge the original authors of the
structural data.