Information card for entry 4081592

Structure parameters

• Formula: C55 H43 B F7 Fe O3 P3 Pt
• Calculated formula: C55 H43 B F7 Fe O3 P3 Pt
• SMILES: [B](F)(F)(F)[F-].c1(ccccc1)[P](c1ccccc1)(c1ccccc1)[Pt]123CC1(c1ccccc1C(F)(F)F)[Fe]2(C#[O])(C#[O])(C#[O])[P](c1ccccc1)(c1ccccc1)C[P]3(c1ccccc1)c1ccccc1
• Title of publication: Reactivity of Silyl-Substituted Iron‒Platinum Hydride Complexes toward Unsaturated Molecules: 4. Insertion of Fluorinated Aromatic Alkynes into the Platinum‒Hydride Bond. Synthesis and Reactivity of Heterobimetallic Dimetallacylopentenone, Dimetallacyclobutene, μ-Vinylidene, and μ2-σ-Alkenyl Complexes
• Authors of publication: Jourdain, Isabelle; Knorr, Michael; Strohmann, Carsten; Unkelbach, Christian; Rojo, Saúl; Gómez-Iglesias, Patricia; Villafañe, Fernando
• Journal of publication: Organometallics
• Year of publication: 2013
• Journal volume: 32
• Journal issue: 19
• Pages of publication: 5343
• a: 11.6738 ± 0.0006 Å
• b: 13.0468 ± 0.0006 Å
• c: 19.1687 ± 0.0009 Å
• α: 104.224 ± 0.004°
• β: 94.549 ± 0.004°
• γ: 108.564 ± 0.005°
• Cell volume: 2643 ± 0.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.064
• Residual factor for significantly intense reflections: 0.0413
• Weighted residual factors for significantly intense reflections: 0.0694
• Weighted residual factors for all reflections included in the refinement: 0.0713
• Goodness-of-fit parameter for all reflections included in the refinement: 1.058
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No