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Information card for entry 4082607
Preview
Coordinates | 4082607.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C15 H19 F3 N2 P Rh |
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Calculated formula | C15 H19 F3 N2 P Rh |
SMILES | c12c(F)nc(c(c1N(C[Rh]13452([cH]2[cH]1[cH]3[cH]4[cH]52)[P](C)(C)C)C)F)F |
Title of publication | Photochemical Reactions of Fluorinated Pyridines at Half-Sandwich Rhodium Complexes: Competing Pathways of Reaction. |
Authors of publication | Procacci, Barbara; Blagg, Robin J.; Perutz, Robin N.; Rendón, Nuria; Whitwood, Adrian C. |
Journal of publication | Organometallics |
Year of publication | 2014 |
Journal volume | 33 |
Journal issue | 1 |
Pages of publication | 45 - 52 |
a | 8.4609 ± 0.0014 Å |
b | 16.312 ± 0.003 Å |
c | 11.9985 ± 0.0019 Å |
α | 90° |
β | 100.907 ± 0.003° |
γ | 90° |
Cell volume | 1626 ± 0.5 Å3 |
Cell temperature | 110 ± 2 K |
Ambient diffraction temperature | 110 K |
Number of distinct elements | 6 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.0398 |
Residual factor for significantly intense reflections | 0.0312 |
Weighted residual factors for significantly intense reflections | 0.077 |
Weighted residual factors for all reflections included in the refinement | 0.0809 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.055 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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The link is: https://www.crystallography.net/4082607.html
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