Information card for entry 4082635

Structure parameters

• Formula: C23 H64 O2 Si9
• Calculated formula: C23 H64 O2 Si9
• SMILES: [Si]1([Si](C)(C)[Si](C)(C)[Si@](OC)([C@@H](C(C)(C)C)O[Si](C)(C)[Si]1(C)C)[Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C.[Si]1([Si](C)(C)[Si](C)(C)[Si@@](OC)([C@H](C(C)(C)C)O[Si](C)(C)[Si]1(C)C)[Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C
• Title of publication: Photoinduced Brook-Type Rearrangement of Acylcyclopolysilanes.
• Authors of publication: Stueger, Harald; Hasken, Bernd; Haas, Michael; Rausch, Martin; Fischer, Roland; Torvisco, Ana
• Journal of publication: Organometallics
• Year of publication: 2014
• Journal volume: 33
• Journal issue: 1
• Pages of publication: 231 - 239
• a: 9.5421 ± 0.0006 Å
• b: 12.289 ± 0.0008 Å
• c: 17.355 ± 0.0011 Å
• α: 97.377 ± 0.003°
• β: 99.925 ± 0.003°
• γ: 99.497 ± 0.003°
• Cell volume: 1951.2 ± 0.2 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0496
• Residual factor for significantly intense reflections: 0.0392
• Weighted residual factors for significantly intense reflections: 0.1014
• Weighted residual factors for all reflections included in the refinement: 0.1094
• Goodness-of-fit parameter for all reflections included in the refinement: 1.049
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No