Information card for entry 4082652

Structure parameters

• Formula: C30 H41 Al2 P
• Calculated formula: C30 H41 Al2 P
• SMILES: C1(=C/c2ccccc2)\[P](c2c(C)cc(C)cc2C)(c2c(C)cc(C)cc2C)[Al]([H][Al]1(C)C)(C)C
• Title of publication: Al/P-Based Frustrated Lewis Pairs: Limitations of Their Synthesis by Hydroalumination and Formation of Dialkylaluminum Hydride Adducts
• Authors of publication: Uhl, Werner; Appelt, Christian; Backs, Jana; Westenberg, Hauke; Wollschläger, Agnes; Tannert, Jens
• Journal of publication: Organometallics
• Year of publication: 2014
• Journal volume: 33
• Journal issue: 5
• Pages of publication: 1212
• a: 9.5503 ± 0.0013 Å
• b: 10.2243 ± 0.0014 Å
• c: 16.075 ± 0.002 Å
• α: 73.34 ± 0.004°
• β: 86.441 ± 0.004°
• γ: 75.193 ± 0.004°
• Cell volume: 1453.7 ± 0.3 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1016
• Residual factor for significantly intense reflections: 0.0761
• Weighted residual factors for significantly intense reflections: 0.1773
• Weighted residual factors for all reflections included in the refinement: 0.1941
• Goodness-of-fit parameter for all reflections included in the refinement: 1.107
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No