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Information card for entry 4082754
Preview
Coordinates | 4082754.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C31 H52 F3 O3 P2 Rh S |
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Calculated formula | C31 H52 F3 O3 P2 Rh S |
SMILES | [Rh]123456([P](C(C)(C)C)(C(C)(C)C)CC[P]1(C(C)(C)C)C(C)(C)C)[cH]1[cH]2[cH]3[cH]4[cH]5[cH]61.S(=O)(=O)([O-])C(F)(F)F.c1ccccc1 |
Title of publication | Synthesis and Reactivity of Three-Coordinate (dtbpe)Rh Silylamides: CO2Bond Cleavage by a Rhodium(I) Disilylamide |
Authors of publication | Whited, Matthew T.; Kosanovich, Alex J.; Janzen, Daron E. |
Journal of publication | Organometallics |
Year of publication | 2014 |
Journal volume | 33 |
Journal issue | 6 |
Pages of publication | 1416 |
a | 10.9982 ± 0.0013 Å |
b | 16.2326 ± 0.0019 Å |
c | 18.993 ± 0.002 Å |
α | 94.414 ± 0.007° |
β | 95.937 ± 0.007° |
γ | 90.425 ± 0.006° |
Cell volume | 3362.2 ± 0.7 Å3 |
Cell temperature | 173 K |
Ambient diffraction temperature | 173 K |
Number of distinct elements | 7 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.0532 |
Residual factor for significantly intense reflections | 0.0373 |
Weighted residual factors for significantly intense reflections | 0.0763 |
Weighted residual factors for all reflections included in the refinement | 0.0825 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.03 |
Diffraction radiation wavelength | 0.71075 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4082754.html
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