Information card for entry 4083395

Structure parameters

• Chemical name: N-((dimethylamino)dimethylsilyl)-2,6-diisopropyl- benzenamino trichlorohafnium lithium
• Formula: C24 H49 Cl4 Hf Li N2 O2 Si
• Calculated formula: C24 H49 Cl4 Hf Li N2 O2 Si
• SMILES: [Hf]12(Cl)(Cl)([Cl][Li]([Cl]1)([O](CC)CC)[O](CC)CC)N([Si]([N]2(C)C)(C)C)c1c(cccc1C(C)C)C(C)C
• Title of publication: μ2,η1-N-[(N,N-Dimethylamino)dimethylsilyl]-2,6-diisopropylanilido Metal (Li, Zr, Hf) Compounds and the Catalytic Behaviors of the IVB Compounds in Ethylene (Co)Polymerizationξ
• Authors of publication: Yuan, Shifang; Wei, Xuehong; Tong, Hongbo; Zhang, Liping; Liu, Diansheng; Sun, Wen-Hua
• Journal of publication: Organometallics
• Year of publication: 2010
• Journal volume: 29
• Journal issue: 9
• Pages of publication: 2085
• a: 14.164 ± 0.002 Å
• b: 14.759 ± 0.003 Å
• c: 17.027 ± 0.003 Å
• α: 90°
• β: 108.485 ± 0.002°
• γ: 90°
• Cell volume: 3375.8 ± 1 ų
• Cell temperature: 203 ± 2 K
• Ambient diffraction temperature: 203 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0412
• Residual factor for significantly intense reflections: 0.0339
• Weighted residual factors for significantly intense reflections: 0.097
• Weighted residual factors for all reflections included in the refinement: 0.1121
• Goodness-of-fit parameter for all reflections included in the refinement: 1.183
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No