Information card for entry 4083901

Structure parameters

• Common name: di-mu-carbonyl-dicarbonyl-bis[2,5-bis(phenyldimethylsilyl)-3,4-dipropyl- cyclopentadienone]dicobalt
• Chemical name: di-mu-carbonyl-dicarbonyl-bis[(2,3,4,5-eta)-2,5-bis[dimethyl(phenyl)silyl]- 3,4-dipropyl-cyclopenta-2,4-dien-1-one]bis[cobalt(0)](Co-Co)
• Formula: C58 H72 Co2 O6 Si4
• Calculated formula: C58 H72 Co2 O6 Si4
• Title of publication: Cyclopentadienone and Hydroxycyclopentadienyl Cobalt Complexes from the Reaction of an Alkynylphenylsilane with Co2(CO)8
• Authors of publication: Hoffmann, Florian; Wagler, Jörg; Roewer, Gerhard
• Journal of publication: Organometallics
• Year of publication: 2014
• Journal volume: 33
• Journal issue: 20
• Pages of publication: 5622
• a: 11.56 ± 0.001 Å
• b: 12.8939 ± 0.0013 Å
• c: 20.363 ± 0.002 Å
• α: 90.082 ± 0.005°
• β: 96.135 ± 0.005°
• γ: 111.999 ± 0.005°
• Cell volume: 2795.2 ± 0.5 ų
• Cell temperature: 93 ± 2 K
• Ambient diffraction temperature: 93 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0607
• Residual factor for significantly intense reflections: 0.0371
• Weighted residual factors for significantly intense reflections: 0.0836
• Weighted residual factors for all reflections included in the refinement: 0.0902
• Goodness-of-fit parameter for all reflections included in the refinement: 1.036
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No