Information card for entry 4083943

Structure parameters

• Chemical name: ([RuCl(p-cymene)(phosphoramidite)]PF6
• Formula: C55.5 H48 Cl4 F6 N O2 P2 Ru
• Calculated formula: C55.5 H48 Cl4 F6 N O2 P2 Ru
• Title of publication: An η2-Aryl−Metal Interaction Turns a Chiral Monodentate Phosphoramidite into a Chelating Ligand in (Sa,SRu,RC,RC)-[RuCl(η6-p-cymene) (O,O‘-(1,1‘-dinaphthyl-2,2‘-diyl)-N-(1-(1,2-η-1-naphthyl)ethyl)-N-(1-(1-naphthyl)ethyl)phosphoramidite-κP)]PF6
• Authors of publication: Huber, Dominik; Kumar, P. G. Anil; Pregosin, Paul S.; Mezzetti, Antonio
• Journal of publication: Organometallics
• Year of publication: 2005
• Journal volume: 24
• Journal issue: 22
• Pages of publication: 5221
• a: 13.304 ± 0.0008 Å
• b: 13.7074 ± 0.0008 Å
• c: 15.135 ± 0.0009 Å
• α: 98.822 ± 0.001°
• β: 96.636 ± 0.001°
• γ: 111.659 ± 0.001°
• Cell volume: 2489.9 ± 0.3 ų
• Cell temperature: 201 ± 2 K
• Ambient diffraction temperature: 201 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0447
• Residual factor for significantly intense reflections: 0.0405
• Weighted residual factors for significantly intense reflections: 0.1079
• Weighted residual factors for all reflections included in the refinement: 0.1112
• Goodness-of-fit parameter for all reflections included in the refinement: 1.033
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No