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Information card for entry 4083989
Preview
Coordinates | 4083989.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C24 H38 F6 N4 P Rh |
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Calculated formula | C24 H38 F6 N4 P Rh |
SMILES | [Rh]1234(=C5N(C=CN5CCCC)CCN5C=1N(C=C5)CCCC)[CH]1=[CH]2CC[CH]3=[CH]4CC1.[P](F)(F)(F)(F)(F)[F-] |
Title of publication | Reactivity Differences in the Syntheses of Chelating N-Heterocyclic Carbene Complexes of Rhodium Are Ascribed to Ligand Anisotropy |
Authors of publication | Mata, José A.; Chianese, Anthony R.; Miecznikowski, John R.; Poyatos, Macarena; Peris, Eduardo; Faller, Jack W.; Crabtree, Robert H. |
Journal of publication | Organometallics |
Year of publication | 2004 |
Journal volume | 23 |
Journal issue | 6 |
Pages of publication | 1253 |
a | 12.3626 ± 0.0003 Å |
b | 15.8246 ± 0.0004 Å |
c | 13.6358 ± 0.0004 Å |
α | 90° |
β | 96.4499 ± 0.001° |
γ | 90° |
Cell volume | 2650.73 ± 0.12 Å3 |
Cell temperature | 183.2 K |
Ambient diffraction temperature | 183.2 K |
Number of distinct elements | 6 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.0973 |
Residual factor for significantly intense reflections | 0.038 |
Weighted residual factors for all reflections | 0.076 |
Weighted residual factors for all reflections included in the refinement | 0.038 |
Goodness-of-fit parameter for all reflections | 1.747 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.19 |
Diffraction radiation wavelength | 0.7107 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4083989.html
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Users of the data should acknowledge the original authors of the
structural data.