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Information card for entry 4084501
Preview
Coordinates | 4084501.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C63 H64 B N4 O3 P2 Rh |
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Calculated formula | C63 H64 B N4 O3 P2 Rh |
SMILES | [RhH]12([P](c3ccccc3)(c3ccccc3)O)([P](c3ccccc3)(c3ccccc3)c3ccccc3C1=O)[N](=C(C(C)=[N]2N)C)N.[B-](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.C1CCCO1 |
Title of publication | Hydrido{(acylphosphine)(diphenylphosphinous acid)}rhodium(III) Complexes. Catalysts for the Homogeneous Hydrolysis of Ammonia- or Amine-Boranes under Air |
Authors of publication | Nacianceno, Virginia San; Ibarlucea, Lourdes; Mendicute-Fierro, Claudio; Rodríguez-Diéguez, Antonio; Seco, José M.; Zumeta, Itziar; Ubide, Carlos; Garralda, María A. |
Journal of publication | Organometallics |
Year of publication | 2014 |
Journal volume | 33 |
Journal issue | 21 |
Pages of publication | 6044 |
a | 19.6092 ± 0.0017 Å |
b | 11.8959 ± 0.001 Å |
c | 23.32 ± 0.002 Å |
α | 90° |
β | 94.238 ± 0.001° |
γ | 90° |
Cell volume | 5425 ± 0.8 Å3 |
Cell temperature | 100 ± 2 K |
Ambient diffraction temperature | 100 ± 2 K |
Number of distinct elements | 7 |
Space group number | 9 |
Hermann-Mauguin space group symbol | C 1 c 1 |
Hall space group symbol | C -2yc |
Residual factor for all reflections | 0.0522 |
Residual factor for significantly intense reflections | 0.0436 |
Weighted residual factors for significantly intense reflections | 0.0898 |
Weighted residual factors for all reflections included in the refinement | 0.0965 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.015 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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The link is: https://www.crystallography.net/4084501.html
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Users of the data should acknowledge the original authors of the
structural data.