Information card for entry 4084667

Structure parameters

• Formula: C24 H54 N P2 Si2 V
• Calculated formula: C24 H54 N P2 Si2 V
• SMILES: [V](=C[Si](C)(C)C)([P](C)(C)C)([P](C)(C)C)(=NC12CC3CC(C1)CC(C2)C3)C[Si](C)(C)C
• Title of publication: Synthesis of (Adamantylmido)vanadium(V)-Alkyl, Alkylidene Complex Trapped with PMe3: Reactions of the Alkylidene Complexes with Phenols
• Authors of publication: Hatagami, Kohei; Nomura, Kotohiro
• Journal of publication: Organometallics
• Year of publication: 2014
• Journal volume: 33
• Journal issue: 22
• Pages of publication: 6585
• a: 10.339 ± 0.003 Å
• b: 10.355 ± 0.003 Å
• c: 17.415 ± 0.005 Å
• α: 101.924 ± 0.003°
• β: 101.373 ± 0.007°
• γ: 105.836 ± 0.013°
• Cell volume: 1690.1 ± 0.9 ų
• Cell temperature: 93 K
• Ambient diffraction temperature: 93 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.0598
• Weighted residual factors for all reflections included in the refinement: 0.1813
• Goodness-of-fit parameter for all reflections included in the refinement: 1.092
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No