Information card for entry 4084962

Structure parameters

• Formula: C36 H55 Co Ru2 Si
• Calculated formula: C36 H55 Co Ru2 Si
• SMILES: [Ru]12345678([H][Ru]9%10%11%12%13%14%15([Co]%16%17%18%191([H]7)([H]%14)([Si]2%12([H]8)([H]%15)c1ccccc1)[c]1([c]%16([c]%17([c]%18([c]%191C)C)C)C)C)[c]1([c]%13([c]9([c]%10([c]%111C)C)C)C)C)[c]1([c]3([c]4([c]5([c]61C)C)C)C)C
• Title of publication: Trinuclear μ3-Silyl Complexes of Ruthenium and Group 9 Metals Having 3c-2e Interactions and Transformation of a μ3-Silyl Complex of Ru2Ir into μ-Silyl and μ3-Silylene Complexes
• Authors of publication: Nagaoka, Masahiro; Shima, Takanori; Takao, Toshiro; Suzuki, Hiroharu
• Journal of publication: Organometallics
• Year of publication: 2014
• Journal volume: 33
• Journal issue: 24
• Pages of publication: 7232
• a: 10.3813 ± 0.0005 Å
• b: 10.8049 ± 0.0005 Å
• c: 17.3097 ± 0.0009 Å
• α: 105.338 ± 0.0014°
• β: 97.365 ± 0.0017°
• γ: 107.459 ± 0.0016°
• Cell volume: 1740.14 ± 0.15 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0424
• Residual factor for significantly intense reflections: 0.0316
• Weighted residual factors for significantly intense reflections: 0.0692
• Weighted residual factors for all reflections included in the refinement: 0.0742
• Goodness-of-fit parameter for all reflections included in the refinement: 1.051
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No