Information card for entry 4084964

Structure parameters

• Formula: C41 H64 Ir N Ru2 Si
• Calculated formula: C41 H60 Ir1.0025 N Ru2.0025 Si
• Title of publication: Trinuclear μ3-Silyl Complexes of Ruthenium and Group 9 Metals Having 3c-2e Interactions and Transformation of a μ3-Silyl Complex of Ru2Ir into μ-Silyl and μ3-Silylene Complexes
• Authors of publication: Nagaoka, Masahiro; Shima, Takanori; Takao, Toshiro; Suzuki, Hiroharu
• Journal of publication: Organometallics
• Year of publication: 2014
• Journal volume: 33
• Journal issue: 24
• Pages of publication: 7232
• a: 11.0572 ± 0.0004 Å
• b: 21.1799 ± 0.0006 Å
• c: 17.6514 ± 0.0005 Å
• α: 90°
• β: 98.034 ± 0.0011°
• γ: 90°
• Cell volume: 4093.2 ± 0.2 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0453
• Residual factor for significantly intense reflections: 0.0376
• Weighted residual factors for significantly intense reflections: 0.0796
• Weighted residual factors for all reflections included in the refinement: 0.083
• Goodness-of-fit parameter for all reflections included in the refinement: 1.046
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No