Information card for entry 4085253

Structure parameters

• Formula: C27 H72 Ce N3 Si6
• Calculated formula: C27 H72 Ce N3 Si6
• SMILES: C(C)(C)(C)[Si](C)(C)N([Si](C)(C)C)[Ce](N([Si](C(C)(C)C)(C)C)[Si](C)(C)C)N([Si](C(C)(C)C)(C)C)[Si](C)(C)C
• Title of publication: Homoleptic Trigonal Planar Lanthanide Complexes Stabilized by Superbulky Silylamide Ligands
• Authors of publication: Goodwin, Conrad A. P.; Joslin, Kristian C.; Lockyer, Selena J.; Formanuik, Alasdair; Morris, Gareth A.; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo. J.; Mills, David P.
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 11
• Pages of publication: 2314
• a: 20.271 ± 0.002 Å
• b: 20.271 ± 0.002 Å
• c: 16.723 ± 0.002 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 5951.1 ± 1.1 ų
• Cell temperature: 150.01 ± 0.12 K
• Ambient diffraction temperature: 150.01 ± 0.12 K
• Number of distinct elements: 5
• Space group number: 161
• Hermann-Mauguin space group symbol: R 3 c :H
• Hall space group symbol: R 3 -2"c
• Residual factor for all reflections: 0.0734
• Residual factor for significantly intense reflections: 0.0389
• Weighted residual factors for significantly intense reflections: 0.071
• Weighted residual factors for all reflections included in the refinement: 0.0821
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No