Information card for entry 4085327

Structure parameters

• Common name: complex_2_amide
• Chemical name: amido(eta-5-pentamethylcyclopentadienyl) (eta-8-(bis{triisopropylsilyl}cyclooctatetraene))uranium(IV)
• Formula: C41 H77 N O Si2 U
• Calculated formula: C41 H78 N O Si2 U
• Title of publication: Synthesis and Reactivity of a Mixed-Sandwich Uranium(IV) Primary Amido Complex
• Authors of publication: Higgins Frey, Jessica A.; Cloke, F. Geoffrey N.; Roe, S. Mark
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 11
• Pages of publication: 2102
• a: 9.2246 ± 0.0001 Å
• b: 20.7046 ± 0.0003 Å
• c: 11.5888 ± 0.0002 Å
• α: 90°
• β: 101.066 ± 0.001°
• γ: 90°
• Cell volume: 2172.21 ± 0.05 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 11
• Hermann-Mauguin space group symbol: P 1 21/m 1
• Hall space group symbol: -P 2yb
• Residual factor for all reflections: 0.0367
• Residual factor for significantly intense reflections: 0.0285
• Weighted residual factors for significantly intense reflections: 0.0593
• Weighted residual factors for all reflections included in the refinement: 0.0617
• Goodness-of-fit parameter for all reflections included in the refinement: 1.025
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No