Information card for entry 4085355

Structure parameters

• Common name: Hf=Ge complex
• Chemical name: Hf-germylene complex
• Formula: C35 H69 Ge Hf P Si2
• Calculated formula: C35 H69 Ge Hf P Si2
• SMILES: [Hf]12345678([Ge]([Si](C)(C(C)(C)C)C(C)(C)C)[Si](C)(C(C)(C)C)C(C)(C)C)([P](C)(C)C)([c]9([cH]1[cH]2[cH]3[cH]49)CC)[c]1([cH]8[cH]7[cH]6[cH]51)CC
• Title of publication: A Schrock-Type Germylene Complex: (η5-C5H4Et)2(PMe3)Hf═Ge(SiMetBu2)2
• Authors of publication: Nakata, Norio; Aoki, Shinji; Lee, Vladimir Ya.; Sekiguchi, Akira
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 11
• Pages of publication: 2699
• a: 19.162 ± 0.0005 Å
• b: 11.805 ± 0.0005 Å
• c: 19.681 ± 0.0009 Å
• α: 90°
• β: 118.26 ± 0.003°
• γ: 90°
• Cell volume: 3921.3 ± 0.3 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.048
• Residual factor for significantly intense reflections: 0.0451
• Weighted residual factors for significantly intense reflections: 0.1201
• Weighted residual factors for all reflections included in the refinement: 0.1259
• Goodness-of-fit parameter for all reflections included in the refinement: 1.094
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No