Information card for entry 4085415

Structure parameters

• Formula: C34 H79 Cl N4 O Si3 Th
• Calculated formula: C28 H65 Cl N4 O Si3 Th
• Title of publication: Thorium Triamidoamine Complexes: Synthesis of an Unusual Dinuclear Tuck-in‒Tuck-over Thorium Metallacycle Featuring the Longest Known Thorium−σ-Alkyl Bond
• Authors of publication: Gardner, Benedict M.; Lewis, William; Blake, Alexander J.; Liddle, Stephen T.
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 11
• Pages of publication: 2386
• a: 14.481 ± 0.005 Å
• b: 20.964 ± 0.007 Å
• c: 22.54 ± 0.007 Å
• α: 71.861 ± 0.005°
• β: 74.644 ± 0.005°
• γ: 81.898 ± 0.005°
• Cell volume: 6258 ± 4 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1808
• Residual factor for significantly intense reflections: 0.0838
• Weighted residual factors for significantly intense reflections: 0.1949
• Weighted residual factors for all reflections included in the refinement: 0.2306
• Goodness-of-fit parameter for all reflections included in the refinement: 1.016
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No