Information card for entry 4085473

Structure parameters

• Formula: C32 H59 N Si6
• Calculated formula: C32 H59 N Si6
• SMILES: [Si]1([Si]([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)(N([Si](C)(C)C)c2c(cccc2C(C)C)C(C)C)C=C1c1ccccc1
• Title of publication: Reactivity of Boryl- and Silyl-Substituted Carbenoids toward Alkynes: Insertion and Cycloaddition Chemistry
• Authors of publication: Protchenko, Andrey V.; Blake, Matthew P.; Schwarz, Andrew D.; Jones, Cameron; Mountford, Philip; Aldridge, Simon
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 11
• Pages of publication: 2126
• a: 9.9961 ± 0.0003 Å
• b: 12.1873 ± 0.0004 Å
• c: 17.8179 ± 0.0005 Å
• α: 101.382 ± 0.003°
• β: 91.531 ± 0.002°
• γ: 113.17 ± 0.003°
• Cell volume: 1943.18 ± 0.12 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0472
• Residual factor for significantly intense reflections: 0.0445
• Weighted residual factors for all reflections: 0.0286
• Weighted residual factors for significantly intense reflections: 0.0278
• Weighted residual factors for all reflections included in the refinement: 0.0276
• Goodness-of-fit parameter for all reflections included in the refinement: 1.1106
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No