Information card for entry 4085746

Structure parameters

• Formula: C23 H30 Co N P2
• Calculated formula: C23 H30 Co N P2
• SMILES: [CoH]12([P](C)(C)C)([P](C)(C)C)[N](c3cccc4cccc1c34)=Cc1c2cccc1
• Title of publication: Synthesis and Reactivity of a Hydrido CNC Pincer Cobalt(III) Complex and Its Application in Hydrosilylation of Aldehydes and Ketones
• Authors of publication: Zhou, Hongwei; Sun, Hongjian; Zhang, Shumiao; Li, Xiaoyan
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 8
• Pages of publication: 1479
• a: 11.3234 ± 0.0003 Å
• b: 12.0617 ± 0.0004 Å
• c: 17.3501 ± 0.0005 Å
• α: 93.508 ± 0.002°
• β: 107.454 ± 0.002°
• γ: 91.315 ± 0.002°
• Cell volume: 2254.2 ± 0.12 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1082
• Residual factor for significantly intense reflections: 0.0969
• Weighted residual factors for significantly intense reflections: 0.2477
• Weighted residual factors for all reflections included in the refinement: 0.255
• Goodness-of-fit parameter for all reflections included in the refinement: 1.044
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No