Information card for entry 4086156

Structure parameters

• Formula: C100 H126 Ge2 N2 Si2
• Calculated formula: C100 H126 Ge2 N2 Si2
• SMILES: [Ge](N([Si](C(C)C)(C(C)C)C(C)C)c1c(cc(cc1C(c1ccccc1)c1ccccc1)C(C)C)C(c1ccccc1)c1ccccc1)[C@H]1C=C[C@@H]([Ge]N([Si](C(C)C)(C(C)C)C(C)C)c2c(cc(cc2C(c2ccccc2)c2ccccc2)C(C)C)C(c2ccccc2)c2ccccc2)CC1.CCCCCC
• Title of publication: Reactivity of Amido-Digermynes, LGeGeL (L = Bulky Amide), toward Olefins and Related Molecules: Facile Reduction, C‒H Activation, and Reversible Cycloaddition of Unsaturated Substrates
• Authors of publication: Hadlington, Terrance J.; Li, Jiaye; Hermann, Markus; Davey, Amelia; Frenking, Gernot; Jones, Cameron
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 13
• Pages of publication: 3175
• a: 13.236 ± 0.003 Å
• b: 17.267 ± 0.004 Å
• c: 21.064 ± 0.004 Å
• α: 69.59 ± 0.03°
• β: 86.91 ± 0.03°
• γ: 76.58 ± 0.03°
• Cell volume: 4387 ± 2 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0949
• Residual factor for significantly intense reflections: 0.0716
• Weighted residual factors for significantly intense reflections: 0.1851
• Weighted residual factors for all reflections included in the refinement: 0.2015
• Goodness-of-fit parameter for all reflections included in the refinement: 1.026
• Diffraction radiation wavelength: 0.7108 Å
• Diffraction radiation type: Synchrotron
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No