Information card for entry 4086453

Structure parameters

• Formula: C32 H46 Ge2 Li2 N4
• Calculated formula: C32 H46 Ge2 Li2 N4
• SMILES: [Ge]123[c]45c6ccc[c]74[CH]4=[N]2(C(C)(C)C)[Li]23574[Ge]34[c]57[Li]8913([N](=C6)C(C)(C)C)[c]7([CH]8=[N]49C(C)(C)C)cccc5C=[N]2C(C)(C)C
• Title of publication: Synthesis of a Germylidenide Anion from the C‒C Bond Activation of a Bis(germylene)
• Authors of publication: Seow, Celestine; Xi, Hong-Wei; Li, Yongxin; So, Cheuk-Wai
• Journal of publication: Organometallics
• Year of publication: 2016
• Journal volume: 35
• Journal issue: 8
• Pages of publication: 1060
• a: 15.099 ± 0.004 Å
• b: 10.77 ± 0.003 Å
• c: 20.223 ± 0.005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3288.6 ± 1.5 ų
• Cell temperature: 133 ± 2 K
• Ambient diffraction temperature: 133 ± 2 K
• Number of distinct elements: 5
• Space group number: 54
• Hermann-Mauguin space group symbol: P c c a
• Hall space group symbol: -P 2a 2ac
• Residual factor for all reflections: 0.1222
• Residual factor for significantly intense reflections: 0.0728
• Weighted residual factors for significantly intense reflections: 0.1523
• Weighted residual factors for all reflections included in the refinement: 0.1724
• Goodness-of-fit parameter for all reflections included in the refinement: 1.09
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No