Information card for entry 4086496

Structure parameters

• Formula: C44 H116 O4 Si12 Sm2
• Calculated formula: C44 H116 O4 Si12 Sm2
• SMILES: C([SiH](C)C)([SiH](C)C)([SiH](C)C)[Sm]([O]1CCCC1)(C([SiH](C)C)([SiH](C)C)[SiH](C)C)[O]1CCCC1
• Title of publication: Homoleptic Divalent Dialkyl Lanthanide-Catalyzed Cross-Dehydrocoupling of Silanes and Amines
• Authors of publication: Pindwal, Aradhana; Ellern, Arkady; Sadow, Aaron D.
• Journal of publication: Organometallics
• Year of publication: 2016
• Journal volume: 35
• Journal issue: 11
• Pages of publication: 1674
• a: 23.181 ± 0.003 Å
• b: 9.3319 ± 0.0011 Å
• c: 18.901 ± 0.002 Å
• α: 90°
• β: 121.725 ± 0.0015°
• γ: 90°
• Cell volume: 3477.8 ± 0.7 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.025
• Residual factor for significantly intense reflections: 0.0211
• Weighted residual factors for significantly intense reflections: 0.0471
• Weighted residual factors for all reflections included in the refinement: 0.049
• Goodness-of-fit parameter for all reflections included in the refinement: 1.035
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No