Information card for entry 4087007

Structure parameters

• Formula: C34.5 H47 Cl3 O1.5 P2 Rh
• Calculated formula: C34.5 H47 Cl3 O1.5 P2 Rh
• Title of publication: Selective C‒Cl Bond Oxidative Addition of Chloroarenes to a POP‒Rhodium Complex
• Authors of publication: Curto, Sheila G.; Esteruelas, Miguel A.; Oliván, Montserrat; Oñate, Enrique; Vélez, Andrea
• Journal of publication: Organometallics
• Year of publication: 2017
• Journal volume: 36
• Journal issue: 1
• Pages of publication: 114
• a: 47.708 ± 0.008 Å
• b: 12.228 ± 0.002 Å
• c: 33.505 ± 0.005 Å
• α: 90°
• β: 133.874 ± 0.002°
• γ: 90°
• Cell volume: 14090 ± 4 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0815
• Residual factor for significantly intense reflections: 0.0622
• Weighted residual factors for significantly intense reflections: 0.1527
• Weighted residual factors for all reflections included in the refinement: 0.1613
• Goodness-of-fit parameter for all reflections included in the refinement: 1.113
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No