Information card for entry 4087044

Structure parameters

• Formula: C64 H70 Cl P Ru S
• Calculated formula: C64 H70 Cl P Ru S
• Title of publication: Hidden Enantioselective Hydrogenation of N-Silyl Enamines and Silyl Enol Ethers in Net C═N and C═O Hydrosilylations Catalyzed by Ru‒S Complexes with One Monodentate Chiral Phosphine Ligand
• Authors of publication: Bähr, Susanne; Oestreich, Martin
• Journal of publication: Organometallics
• Year of publication: 2017
• Journal volume: 36
• Journal issue: 4
• Pages of publication: 935
• a: 16.63401 ± 0.00006 Å
• b: 17.02047 ± 0.00006 Å
• c: 18.94559 ± 0.00007 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5363.85 ± 0.03 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 0.1 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0187
• Residual factor for significantly intense reflections: 0.0183
• Weighted residual factors for significantly intense reflections: 0.0482
• Weighted residual factors for all reflections included in the refinement: 0.0485
• Goodness-of-fit parameter for all reflections included in the refinement: 1.036
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No