Information card for entry 4087860

Structure parameters

• Common name: [(PMe)3Au(MeCN)]4-(POM)2
• Formula: C28 H60 Au4 N8 O40 P4 Si W12
• Calculated formula: C28 H60 Au4 N8 O40 P4 Si W12
• Title of publication: Polyoxometalate-Gold(I)/H+ Complexes: Air-Stable, Efficient, Polyvalent, and Bifunctional Catalysts
• Authors of publication: Hueber, Damien; Hoffmann, Marie; de Frémont, Pierre; Pale, Patrick; Blanc, Aurélien
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 20
• Pages of publication: 5065
• a: 16.1463 ± 0.0004 Å
• b: 12.769 ± 0.0002 Å
• c: 23.6131 ± 0.0005 Å
• α: 90°
• β: 130.002 ± 0.001°
• γ: 90°
• Cell volume: 3729.27 ± 0.15 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 8
• Space group number: 13
• Hermann-Mauguin space group symbol: P 1 2/c 1
• Hall space group symbol: -P 2yc
• Residual factor for all reflections: 0.0631
• Residual factor for significantly intense reflections: 0.0532
• Weighted residual factors for significantly intense reflections: 0.1346
• Weighted residual factors for all reflections included in the refinement: 0.1395
• Goodness-of-fit parameter for all reflections included in the refinement: 1.143
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No