Information card for entry 4087995

Structure parameters

• Formula: C29 H59 B O Os P2
• Calculated formula: C29 H59 B O Os P2
• SMILES: [OsH]1([P](C(C)C)(C(C)C)C(C)C)([H][BH](c2c(c(cc(c2C)C)C)C)[H]1)([P](C(C)C)(C(C)C)C(C)C)C#[O]
• Title of publication: Aryldihydroborane Coordination to Iridium and Osmium Hydrido Complexes
• Authors of publication: Arnold, Nicole; Mozo, Silvia; Paul, Ursula; Radius, Udo; Braunschweig, Holger
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 24
• Pages of publication: 5709
• a: 13.1913 ± 0.0005 Å
• b: 12.495 ± 0.0004 Å
• c: 19.7457 ± 0.0007 Å
• α: 90°
• β: 97.659 ± 0.001°
• γ: 90°
• Cell volume: 3225.6 ± 0.2 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0395
• Residual factor for significantly intense reflections: 0.0236
• Weighted residual factors for significantly intense reflections: 0.041
• Weighted residual factors for all reflections included in the refinement: 0.0448
• Goodness-of-fit parameter for all reflections included in the refinement: 1.034
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No