Information card for entry 4088025

Structure parameters

• Formula: C87 H106 Cl2 I4 N8 O P4 Rh2
• Calculated formula: C86 H102 I4 N8 P4 Rh2
• Title of publication: Synthesis, Isomerization, and Catalytic Transfer Hydrogenation Activity of Rhodium(III) Complexes Containing Both Chelating Dicarbenes and Diphosphine Ligands
• Authors of publication: Farrell, Kevin; Müller-Bunz, Helge; Albrecht, Martin
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 24
• Pages of publication: 5723
• a: 21.0952 ± 0.0002 Å
• b: 13.1999 ± 0.0001 Å
• c: 34.2129 ± 0.0003 Å
• α: 90°
• β: 109.683 ± 0.001°
• γ: 90°
• Cell volume: 8970.09 ± 0.15 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0356
• Residual factor for significantly intense reflections: 0.0337
• Weighted residual factors for significantly intense reflections: 0.0839
• Weighted residual factors for all reflections included in the refinement: 0.085
• Goodness-of-fit parameter for all reflections included in the refinement: 1.072
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No