Information card for entry 4088107

Structure parameters

• Chemical name: Chloro-carbonyl-(tricyclohexylphosphine) -(ferrocenyl-n-propylamino-carbene)-rhodium
• Formula: C32 H47 Cl Fe O2 P Rh
• Calculated formula: C32 H47 Cl Fe O2 P Rh
• Title of publication: Rhodium(I) Ferrocenylcarbene Complexes: Synthesis, Structural Determination, Electrochemistry, and Application as Hydroformylation Catalyst Precursors
• Authors of publication: Ramollo, G. Kabelo; López-Gómez, María J.; Liles, David C.; Matsinha, Leah C.; Smith, Gregory S.; Bezuidenhout, Daniela I.
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 24
• Pages of publication: 5745
• a: 11.3093 ± 0.001 Å
• b: 25.726 ± 0.002 Å
• c: 10.9898 ± 0.001 Å
• α: 90°
• β: 101.349 ± 0.003°
• γ: 90°
• Cell volume: 3134.9 ± 0.5 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0547
• Residual factor for significantly intense reflections: 0.0362
• Weighted residual factors for significantly intense reflections: 0.0668
• Weighted residual factors for all reflections included in the refinement: 0.0711
• Goodness-of-fit parameter for all reflections included in the refinement: 1.102
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No