Information card for entry 4088321

Structure parameters

• Formula: C62 H50 Cl2 Ge Ir O P3
• Calculated formula: C62 H50 Cl2 Ge Ir O P3
• Title of publication: Transition-Metal-Mediated Germanium‒Fluorine Activation: Inverse Electron Flow in σ-Bond Metathesis
• Authors of publication: Kameo, Hajime; Ikeda, Koki; Bourissou, Didier; Sakaki, Shigeyoshi; Takemoto, Shin; Nakazawa, Hiroshi; Matsuzaka, Hiroyuki
• Journal of publication: Organometallics
• Year of publication: 2016
• Journal volume: 35
• Journal issue: 5
• Pages of publication: 713
• a: 10.5656 ± 0.0002 Å
• b: 11.1147 ± 0.0002 Å
• c: 22.8124 ± 0.0005 Å
• α: 81.019 ± 0.003°
• β: 80.133 ± 0.003°
• γ: 84.857 ± 0.004°
• Cell volume: 2601.51 ± 0.09 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0415
• Residual factor for significantly intense reflections: 0.0348
• Weighted residual factors for significantly intense reflections: 0.0653
• Weighted residual factors for all reflections included in the refinement: 0.0693
• Goodness-of-fit parameter for all reflections included in the refinement: 1.063
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No