Information card for entry 4088667

Structure parameters

• Common name: Co(H)(CNArMes2)4
• Chemical name: hydridotetrakis(2,6-dimesitylphenylioscyanide)cobalt
• Formula: C110 H125 Co N4
• Calculated formula: C110 H125 Co N4
• Title of publication: A Well-Defined Isocyano Analogue of HCo(CO)4. 1: Synthesis, Decomposition, and Catalytic 1,1-Hydrogenation of Isocyanides
• Authors of publication: Carpenter, Alex E.; Rheingold, Arnold L.; Figueroa, Joshua S.
• Journal of publication: Organometallics
• Year of publication: 2016
• Journal volume: 35
• Journal issue: 14
• Pages of publication: 2309
• a: 29.856 ± 0.003 Å
• b: 11.6893 ± 0.0011 Å
• c: 27.498 ± 0.003 Å
• α: 90°
• β: 111.766 ± 0.002°
• γ: 90°
• Cell volume: 8912.5 ± 1.6 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 4
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0945
• Residual factor for significantly intense reflections: 0.0564
• Weighted residual factors for significantly intense reflections: 0.1455
• Weighted residual factors for all reflections included in the refinement: 0.168
• Goodness-of-fit parameter for all reflections included in the refinement: 1.022
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No