Information card for entry 4088720

Structure parameters

• Formula: C24 H19 O5 P W
• Calculated formula: C24 H19 O5 P W
• SMILES: [O]#C[W](C#[O])(C#[O])(C#[O])(C#[O])[P@]1([C@@H]2[C@@H]3[C@@H](C[C@H]2CC3)c2c1cccc2)c1ccccc1.[O]#C[W](C#[O])(C#[O])(C#[O])(C#[O])[P@@]1([C@H]2[C@H]3[C@H](C[C@@H]2CC3)c2c1cccc2)c1ccccc1
• Title of publication: Phosphorus‒Carbon Bond Forming Reactions of Diphenylphosphenium and Diphenylphosphine Triflate Complexes of Tungsten
• Authors of publication: Jayaraman, Arumugam; Sterenberg, Brian T.
• Journal of publication: Organometallics
• Year of publication: 2016
• Journal volume: 35
• Journal issue: 14
• Pages of publication: 2367
• a: 15.8721 ± 0.0011 Å
• b: 10.4975 ± 0.0007 Å
• c: 13.7225 ± 0.0009 Å
• α: 90°
• β: 107.02 ± 0.001°
• γ: 90°
• Cell volume: 2186.3 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0144
• Residual factor for significantly intense reflections: 0.0132
• Weighted residual factors for significantly intense reflections: 0.0329
• Weighted residual factors for all reflections included in the refinement: 0.0334
• Goodness-of-fit parameter for all reflections included in the refinement: 1.061
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No