Information card for entry 4088858

Structure parameters

• Formula: C48 H53 Ag B Cl8 F O6 Os2 P4
• Calculated formula: C48 H53 Ag B Cl8 F O6 Os2 P4
• SMILES: [Os](C#[O])([P](C)(C)C)([Ag][Os]([P](C)(C)C)([P](C)(C)C)(C#[O])(C#[O])C#[O])(C#[O])(C#[O])[P](C)(C)C.Clc1cc([B-](c2cc(Cl)cc(Cl)c2)(c2cc(Cl)cc(Cl)c2)c2cc(Cl)cc(Cl)c2)cc(Cl)c1.Fc1ccccc1
• Title of publication: Metal-Only Lewis Pairs Based on Zerovalent Osmium
• Authors of publication: Bissert, Robin; Braunschweig, Holger; Dewhurst, Rian D.; Schneider, Christoph
• Journal of publication: Organometallics
• Year of publication: 2016
• Journal volume: 35
• Journal issue: 15
• Pages of publication: 2567
• a: 16.844 ± 0.005 Å
• b: 16.981 ± 0.003 Å
• c: 21.462 ± 0.006 Å
• α: 90°
• β: 102.34 ± 0.02°
• γ: 90°
• Cell volume: 5997 ± 3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 9
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0322
• Residual factor for significantly intense reflections: 0.0227
• Weighted residual factors for significantly intense reflections: 0.047
• Weighted residual factors for all reflections included in the refinement: 0.0503
• Goodness-of-fit parameter for all reflections included in the refinement: 1.072
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No