Information card for entry 4089131

Structure parameters

• Formula: C24 H58 O Pt Si7
• Calculated formula: C24 H58 O Pt Si7
• SMILES: [CH2]1=[CH]2[Pt]31([CH2]=[CH]3[Si](C)(C)O[Si]2(C)C)=[Si]1C(CCC1([Si](C)(C)C)[Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C
• Title of publication: A Dialkylsilylene-Pt(0) Complex with a DVTMS Ligand for the Catalytic Hydrosilylation of Functional Olefins
• Authors of publication: Iimura, Tomohiro; Akasaka, Naohiko; Iwamoto, Takeaki
• Journal of publication: Organometallics
• Year of publication: 2016
• Journal volume: 35
• Journal issue: 24
• Pages of publication: 4071
• a: 9.4996 ± 0.0019 Å
• b: 17.176 ± 0.003 Å
• c: 21.292 ± 0.004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3474.1 ± 1.1 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0238
• Residual factor for significantly intense reflections: 0.0196
• Weighted residual factors for significantly intense reflections: 0.0394
• Weighted residual factors for all reflections included in the refinement: 0.0403
• Goodness-of-fit parameter for all reflections included in the refinement: 0.837
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No